Please read the instruction before bidding. Chemistry tutor preferred.
Instructions:
Please complete the Chemical Inventory. The three safety data sheets for the chemicals listed on the inventory have been provided below. Once you have completed the inventory, please upload your document using the submission link in this assignment.
Example inventory sheet is attached “Chemical Inventory Example”
Chemical Inventory Homework Assignment:
Safety Data Sheets for the following chemicals will be sent directly to the tutor once bid is accepted.
hydrochloric-acid-concentrate-certified-acs-fisher-chemical.pdf
propylene-oxide-reagent-fisher-chemical.pdf
reagent alcohol (ethyl).pdf
2022 CHEMICAL INVENTORY
Department of Pathology, Immunohistochemistry Laboratory / West Bldg Room 205
Location:
CHEMICALS CABINET
Chemical
CAS #
Vendor
Calcium Chloride
10043-52-4
Cupric Sulfate
Toxicity
Chronic (C)
Health Hazard Flammable Reactivity Carcinogen or Acute (A)
Reproductive
Toxicity
PPE
Blue
Red
Yelow
Lab coat for all
Fisher
2
0
1
Gloves/Lab coat
7758-98-7
Fisher
2
0
1
DAKO TBS
None
DAKO
2
0
2
Gloves/Lab coat
Fast Green
2353-45-9
Sigma
3
0
0
Gloves/Lab coat/Safety glasses/Respirator
Trizma Base
201-064-4
Sigma
0
0
0
Gloves/Lab coat
Trizma Hydrochloride
1185-53-1
Sigma
2
0
0
Gloves/Lab coat
Tween 20
None
Dako
0
0
0
Gloves/Lab coat
WARNING: If
accidental contact
occurs refer to SDS,
Call EHS 243-0000
and Contact
Pathology
Administrator 5851234
Note** Decant/pour all hazardous chemicals as specified in MSDS.
UPDATED: 1/2/2019 ABC
No
Hazard Rating:
0 Minimal
1 Slight
2 Moderate
3 Serious
4 Severe
(A)
No
Gloves/Lab coat/Safety glasses/Respirator
2022 CHEMICAL INVENTORY
Department of Pathology, Immunohistochemistry Laboratory / West Bldg Room 205
Location:
CHEMICALS CABINET
Chemical
CAS #
Vendor
Calcium Chloride
10043-52-4
Cupric Sulfate
Toxicity
Chronic (C)
Health Hazard Flammable Reactivity Carcinogen or Acute (A)
Reproductive
Toxicity
PPE
Blue
Red
Yelow
Lab coat for all
Fisher
2
0
1
Gloves/Lab coat
7758-98-7
Fisher
2
0
1
DAKO TBS
None
DAKO
2
0
2
Gloves/Lab coat
Fast Green
2353-45-9
Sigma
3
0
0
Gloves/Lab coat/Safety glasses/Respirator
Trizma Base
201-064-4
Sigma
0
0
0
Gloves/Lab coat
Trizma Hydrochloride
1185-53-1
Sigma
2
0
0
Gloves/Lab coat
Tween 20
None
Dako
0
0
0
Gloves/Lab coat
WARNING: If
accidental contact
occurs refer to SDS,
Call EHS 243-0000
and Contact
Pathology
Administrator 5851234
Note** Decant/pour all hazardous chemicals as specified in MSDS.
UPDATED: 1/2/2019 ABC
No
Hazard Rating:
0 Minimal
1 Slight
2 Moderate
3 Serious
4 Severe
(A)
No
Gloves/Lab coat/Safety glasses/Respirator
2022 CHEMICAL INVENTORY
Department of Pathology, Immunohistochemistry Laboratory / West Bldg Room 205
Location:
CHEMICALS CABINET
Chemical
CAS #
Vendor
Calcium Chloride
10043-52-4
Cupric Sulfate
Toxicity
Chronic (C)
Health Hazard Flammable Reactivity Carcinogen or Acute (A)
Reproductive
Toxicity
PPE
Blue
Red
Yelow
Lab coat for all
Fisher
2
0
1
Gloves/Lab coat
7758-98-7
Fisher
2
0
1
DAKO TBS
None
DAKO
2
0
2
Gloves/Lab coat
Fast Green
2353-45-9
Sigma
3
0
0
Gloves/Lab coat/Safety glasses/Respirator
Trizma Base
201-064-4
Sigma
0
0
0
Gloves/Lab coat
Trizma Hydrochloride
1185-53-1
Sigma
2
0
0
Gloves/Lab coat
Tween 20
None
Dako
0
0
0
Gloves/Lab coat
WARNING: If
accidental contact
occurs refer to SDS,
Call EHS 243-0000
and Contact
Pathology
Administrator 5851234
Note** Decant/pour all hazardous chemicals as specified in MSDS.
UPDATED: 1/2/2019 ABC
No
Hazard Rating:
0 Minimal
1 Slight
2 Moderate
3 Serious
4 Severe
(A)
No
Gloves/Lab coat/Safety glasses/Respirator
CHEMICAL INVENTORY EXERCISE
Hazard Communication Standard or “Right to Know” Standard
Name of Institution:
Location:
Listed below are chemicals which are a health hazard, flammable, reactive, carcinogenic or toxic.
Chemical Name
CAS #
Vendor
Health
Hazard
Blue
Flammable
Red
Reactivity
Yelow
Carcinogen
Toxicity
Chronic (C) or
Acute (A)
Hazard Rating:
NOTE
Reproductive
Toxicity
Hydrochloric Acid
Reagent Alchol (Ethyl)
Propylene Oxide
Note** Decant/pour
all hazardous
chemicals as
specified in MSDS.
WARNING: If accidental
contact occurs refer to
SDS, Call EHS 243-0000
and Contact Pathology
Administrator 585-1234
UPDATED: 09/09/2019
0 Minimal
1 Slight
2 Moderate
3 Serious
4 Severe
n/a = not applicable
PPE
CHEMICAL INVENTORY EXERCISE
Hazard Communication Standard or “Right to Know” Standard
Name of Institution:
Location:
Listed below are chemicals which are a health hazard, flammable, reactive, carcinogenic or toxic.
Chemical Name
CAS #
Vendor
Health
Hazard
Blue
Flammable
Red
Reactivity
Yelow
Carcinogen
Toxicity
Chronic (C) or
Acute (A)
Hazard Rating:
NOTE
Reproductive
Toxicity
Hydrochloric Acid
Reagent Alchol (Ethyl)
Propylene Oxide
Note** Decant/pour
all hazardous
chemicals as
specified in MSDS.
WARNING: If accidental
contact occurs refer to
SDS, Call EHS 243-0000
and Contact Pathology
Administrator 585-1234
UPDATED: 09/09/2019
0 Minimal
1 Slight
2 Moderate
3 Serious
4 Severe
n/a = not applicable
PPE
SIGMA-ALDRICH
sigma-aldrich.com
SAFETY DATA SHEET
Version 5.8
Revision Date 09/23/2016
Print Date 02/25/2018
1. PRODUCT AND COMPANY IDENTIFICATION
1.1
1.2
Product identifiers
Product name
:
Reagent alcohol
Product Number
Brand
:
:
362808
Aldrich
CAS-No.
:
64-17-5
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
1.3
1.4
:
Laboratory chemicals, Synthesis of substances
Details of the supplier of the safety data sheet
Company
:
Sigma-Aldrich
3050 Spruce Street
SAINT LOUIS MO 63103
USA
Telephone
Fax
:
:
+1 800-325-5832
+1 800-325-5052
Emergency telephone number
Emergency Phone #
:
+1-703-527-3887 (CHEMTREC)
2. HAZARDS IDENTIFICATION
2.1
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 2), H225
Acute toxicity, Oral (Category 4), H302
Eye irritation (Category 2A), H319
Specific target organ toxicity – single exposure (Category 1), H370
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2
GHS Label elements, including precautionary statements
Pictogram
Signal word
Danger
Hazard statement(s)
H225
H302
H319
H370
Highly flammable liquid and vapour.
Harmful if swallowed.
Causes serious eye irritation.
Causes damage to organs.
Precautionary statement(s)
P210
P233
P240
P241
P242
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ ventilating/ lighting/ equipment.
Use only non-sparking tools.
Aldrich – 362808
Page 1 of 11
P243
P260
P264
P270
P280
P301 + P312 + P330
Take precautionary measures against static discharge.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves/ eye protection/ face protection.
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
Rinse mouth.
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
IF exposed: Call a POISON CENTER or doctor/ physician.
If eye irritation persists: Get medical advice/ attention.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to
extinguish.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/ container to an approved waste disposal plant.
P303 + P361 + P353
P305 + P351 + P338
P307 + P311
P337 + P313
P370 + P378
P403 + P235
P405
P501
2.3
Hazards not otherwise classified (HNOC) or not covered by GHS – none
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2
Mixtures
Synonyms
:
Absolute alcohol
Ethyl alcohol, Reagent alcohol
Formula
Molecular weight
:
:
C2H6O
46.07 g/mol
Hazardous components
Component
Classification
Concentration
Ethanol
CAS-No.
EC-No.
Index-No.
64-17-5
200-578-6
603-002-00-5
Flam. Liq. 2; Eye Irrit. 2A;
H225, H319
>= 90 – = 5 – < 10 %
2-Propanol
CAS-No.
EC-No.
Index-No.
67-63-0
200-661-7
603-117-00-0
Flam. Liq. 2; Eye Irrit. 2A;
STOT SE 3; H225, H319,
H336
>= 5 – < 10 %
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
4.1
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
Aldrich - 362808
Page 2 of 11
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a
physician.
4.2
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3
Indication of any immediate medical attention and special treatment needed
No data available
5. FIREFIGHTING MEASURES
5.1
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2
Special hazards arising from the substance or mixture
No data available
5.3
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4
Further information
Use water spray to cool unopened containers.
6. ACCIDENTAL RELEASE MEASURES
6.1
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all
sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
For personal protection see section 8.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in
container for disposal according to local regulations (see section 13).
6.4
Reference to other sections
For disposal see section 13.
7. HANDLING AND STORAGE
7.1
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Use explosion-proof equipment.Keep away from sources of ignition - No smoking.Take measures to prevent the build
up of electrostatic charge.
For precautions see section 2.2.
7.2
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage.
Moisture sensitive. Handle and store under inert gas.
7.3
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Aldrich - 362808
Page 3 of 11
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1
Control parameters
Components with workplace control parameters
Component
CAS-No.
Value
Control
parameters
Ethanol
64-17-5
TWA
1,000.000000
ppm
Remarks
Methanol
67-56-1
Basis
USA. ACGIH Threshold Limit Values
(TLV)
Upper Respiratory Tract irritation
Confirmed animal carcinogen with unknown relevance to humans
TWA
1,000 ppm
USA. OSHA - TABLE Z-1 Limits for
1,900 mg/m3
Air Contaminants - 1910.1000
TWA
1,000 ppm
USA. Occupational Exposure Limits
1,900 mg/m3
(OSHA) - Table Z-1 Limits for Air
Contaminants
The value in mg/m3 is approximate.
TWA
1,000.000000
USA. Occupational Exposure Limits
ppm
(OSHA) - Table Z-1 Limits for Air
1,900.000000
Contaminants
mg/m3
The value in mg/m3 is approximate.
TWA
1,000.000000
USA. NIOSH Recommended
ppm
Exposure Limits
1,900.000000
mg/m3
STEL
1,000.000000
USA. ACGIH Threshold Limit Values
ppm
(TLV)
Upper Respiratory Tract irritation
Confirmed animal carcinogen with unknown relevance to humans
TWA
200.000000
USA. ACGIH Threshold Limit Values
ppm
(TLV)
Headache
Nausea
Dizziness
Eye damage
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Danger of cutaneous absorption
STEL
250.000000
USA. ACGIH Threshold Limit Values
ppm
(TLV)
Headache
Nausea
Dizziness
Eye damage
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Danger of cutaneous absorption
TWA
200.000000
USA. NIOSH Recommended
ppm
Exposure Limits
260.000000
mg/m3
Potential for dermal absorption
Aldrich - 362808
Page 4 of 11
ST
250.000000
USA. NIOSH Recommended
ppm
Exposure Limits
325.000000
mg/m3
Potential for dermal absorption
TWA
200.000000
USA. Occupational Exposure Limits
ppm
(OSHA) - Table Z-1 Limits for Air
260.000000
Contaminants
mg/m3
The value in mg/m3 is approximate.
TWA
200 ppm
USA. ACGIH Threshold Limit Values
(TLV)
Headache
Nausea
Dizziness
Eye damage
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Danger of cutaneous absorption
STEL
250 ppm
USA. ACGIH Threshold Limit Values
(TLV)
Headache
Nausea
Dizziness
Eye damage
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Danger of cutaneous absorption
TWA
200 ppm
USA. NIOSH Recommended
260 mg/m3
Exposure Limits
Potential for dermal absorption
ST
250 ppm
USA. NIOSH Recommended
325 mg/m3
Exposure Limits
Potential for dermal absorption
TWA
200 ppm
USA. Occupational Exposure Limits
260 mg/m3
(OSHA) - Table Z-1 Limits for Air
Contaminants
The value in mg/m3 is approximate.
STEL
250 ppm
USA. OSHA - TABLE Z-1 Limits for
325 mg/m3
Air Contaminants - 1910.1000
Skin notation
TWA
200 ppm
USA. OSHA - TABLE Z-1 Limits for
260 mg/m3
Air Contaminants - 1910.1000
Skin notation
C
1,000 ppm
California permissible exposure
limits for chemical contaminants
(Title 8, Article 107)
Skin
PEL
200 ppm
California permissible exposure
260 mg/m3
limits for chemical contaminants
(Title 8, Article 107)
Skin
STEL
250 ppm
California permissible exposure
325 mg/m3
limits for chemical contaminants
(Title 8, Article 107)
Skin
Aldrich - 362808
Page 5 of 11
2-Propanol
67-63-0
TWA
200.000000
ppm
USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
Upper Respiratory Tract irritation
Eye irritation
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Not classifiable as a human carcinogen
TWA
200 ppm
USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
Upper Respiratory Tract irritation
Eye irritation
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Not classifiable as a human carcinogen
STEL
400 ppm
USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
Upper Respiratory Tract irritation
Eye irritation
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Not classifiable as a human carcinogen
STEL
400.000000
USA. ACGIH Threshold Limit Values
ppm
(TLV)
Central Nervous System impairment
Upper Respiratory Tract irritation
Eye irritation
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Not classifiable as a human carcinogen
TWA
400.000000
USA. Occupational Exposure Limits
ppm
(OSHA) - Table Z-1 Limits for Air
980.000000
Contaminants
mg/m3
The value in mg/m3 is approximate.
TWA
400.000000
USA. NIOSH Recommended
ppm
Exposure Limits
980.000000
mg/m3
ST
500.000000
USA. NIOSH Recommended
ppm
Exposure Limits
1,225.000000
mg/m3
PEL
400 ppm
California permissible exposure
980 mg/m3
limits for chemical contaminants
(Title 8, Article 107)
STEL
500 ppm
California permissible exposure
1,225 mg/m3
limits for chemical contaminants
(Title 8, Article 107)
Biological occupational exposure limits
Component
CAS-No.
Parameters
Methanol
Aldrich - 362808
67-56-1
Methanol
Value
Biological
specimen
Basis
15.0000
mg/l
Urine
ACGIH - Biological
Exposure Indices
(BEI)
Page 6 of 11
Remarks
2-Propanol
8.2
67-63-0
End of shift (As soon as possible after exposure ceases)
Methanol
15 mg/l
Urine
ACGIH - Biological
Exposure Indices
(BEI)
End of shift (As soon as possible after exposure ceases)
Acetone
40.0000
Urine
ACGIH - Biological
mg/l
Exposure Indices
(BEI)
End of shift at end of workweek
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of
workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Full contact
Material: butyl-rubber
Minimum layer thickness: 0.3 mm
Break through time: 480 min
Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.2 mm
Break through time: 30 min
Material tested:Dermatril® P (KCL 743 / Aldrich Z677388, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method:
EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the
supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an
industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It
should not be construed as offering an approval for any specific use scenario.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of
protective equipment must be selected according to the concentration and amount of the dangerous substance
at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.
If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1
Information on basic physical and chemical properties
a)
Appearance
Form: liquid
b)
Odour
No data available
Aldrich - 362808
Page 7 of 11
9.2
c)
Odour Threshold
No data available
d)
pH
No data available
e)
Melting point/freezing
point
Melting point/range: -130 °C (-202 °F)
f)
Initial boiling point and
boiling range
78 °C (172 °F) at 1,013 hPa (760 mmHg)
g)
Flash point
9 °C (48 °F) - closed cup
h)
Evaporation rate
No data available
i)
Flammability (solid, gas) No data available
j)
Upper/lower
flammability or
explosive limits
Upper explosion limit: 24.5 %(V)
Lower explosion limit: 3.3 %(V)
k)
Vapour pressure
59.5 hPa (44.6 mmHg) at 20 °C (68 °F)
l)
Vapour density
No data available
m) Relative density
0.785 g/cm3
n)
Water solubility
No data available
o)
Partition coefficient: noctanol/water
No data available
p)
Auto-ignition
temperature
362 °C (684 °F)
q)
Decomposition
temperature
No data available
r)
Viscosity
No data available
s)
Explosive properties
No data available
t)
Oxidizing properties
No data available
Other safety information
No data available
10. STABILITY AND REACTIVITY
10.1
Reactivity
No data available
10.2
Chemical stability
Stable under recommended storage conditions.
10.3
Possibility of hazardous reactions
Vapours may form explosive mixture with air.
10.4
Conditions to avoid
Heat, flames and sparks.
10.5
Incompatible materials
Aluminium, Acids, Oxidizing agents, Alkali metals, Halogenated compounds, Ammonia, Acid chlorides, Acid
anhydrides, Reducing agents, Peroxides
10.6
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Other decomposition products - No data available
In the event of fire: see section 5
Aldrich - 362808
Page 8 of 11
11. TOXICOLOGICAL INFORMATION
11.1
Information on toxicological effects
Acute toxicity
No data available
Inhalation: No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated., Central nervous system depression, Gastrointestinal disturbance, Nausea, Dizziness, Headache,
narcosis, May cause convulsions.
Stomach - Irregularities - Based on Human Evidence
Kidney - Irregularities - Based on Human Evidence
Stomach - Irregularities - Based on Human Evidence (Ethanol)
Stomach - Irregularities - Based on Human Evidence (Methanol)
Kidney - Irregularities - Based on Human Evidence (2-Propanol)
12. ECOLOGICAL INFORMATION
12.1
Toxicity
No data available
12.2
Persistence and degradability
No data available
Aldrich - 362808
Page 9 of 11
12.3
Bioaccumulative potential
No data available
12.4
Mobility in soil
No data available
12.5
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6
Other adverse effects
No data available
13. DISPOSAL CONSIDERATIONS
13.1
Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this
material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a
licensed professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
DOT (US)
UN number: 1170
Class: 3
Proper shipping name: Ethanol solutions
Reportable Quantity (RQ):
Packing group: II
Poison Inhalation Hazard: No
IMDG
UN number: 1170
Class: 3
Proper shipping name: ETHANOL SOLUTION
Packing group: II
IATA
UN number: 1170
Class: 3
Proper shipping name: Ethanol solution
Packing group: II
EMS-No: F-E, S-D
15. REGULATORY INFORMATION
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
CAS-No.
Revision Date
Methanol
67-56-1
2007-07-01
2-Propanol
67-63-0
1987-01-01
SARA 311/312 Hazards
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
Ethanol
Methanol
2-Propanol
CAS-No.
64-17-5
67-56-1
67-63-0
Revision Date
2007-03-01
2007-07-01
1987-01-01
CAS-No.
64-17-5
67-56-1
67-63-0
Revision Date
2007-03-01
2007-07-01
1987-01-01
Pennsylvania Right To Know Components
Ethanol
Methanol
2-Propanol
Aldrich - 362808
Page 10 of 11
New Jersey Right To Know Components
Ethanol
Methanol
2-Propanol
California Prop. 65 Components
WARNING: This product contains a chemical known to the
State of California to cause birth defects or other reproductive
harm.
Methanol
CAS-No.
64-17-5
67-56-1
67-63-0
Revision Date
2007-03-01
2007-07-01
1987-01-01
CAS-No.
67-56-1
Revision Date
2012-03-16
16. OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.
Acute Tox.
Eye Irrit.
Flam. Liq.
H225
H301 + H311 +
H331
H302
H319
H336
H370
STOT SE
Acute toxicity
Eye irritation
Flammable liquids
Highly flammable liquid and vapour.
Toxic if swallowed, in contact with skin or if inhaled
Harmful if swallowed.
Causes serious eye irritation.
May cause drowsiness or dizziness.
Causes damage to organs.
Specific target organ toxicity - single exposure
HMIS Rating
Health hazard:
Chronic Health Hazard:
Flammability:
Physical Hazard
2
*
3
0
NFPA Rating
Health hazard:
Fire Hazard:
Reactivity Hazard:
2
3
0
Further information
Copyright 2016 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a
guide. The information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the
product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling
or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing
slip for additional terms and conditions of sale.
Preparation Information
Sigma-Aldrich Corporation
Product Safety – Americas Region
1-800-521-8956
Version: 5.8
Aldrich - 362808
Revision Date: 09/23/2016
Print Date: 02/25/2018
Page 11 of 11
SAFETY DATA SHEET
Creation Date 15-Feb-2010
Revision Date 18-Jan-2018
Revision Number 3
1. Identification
Product Name
Hydrochloric acid solution, 1N
Cat No. :
SA55; S748561
Synonyms
Muriatic acid solution; Hydrogen chloride solution (Certified)
Recommended Use
Uses advised against
Laboratory chemicals.
Not for food, drug, pesticide or biocidal product use
Details of the supplier of the safety data sheet
Company
Fisher Scientific
One Reagent Lane
Fair Lawn, NJ 07410
Tel: (201) 796-7100
Emergency Telephone Number
CHEMTRECÒ, Inside the USA: 800-424-9300
CHEMTRECÒ, Outside the USA: 001-703-527-3887
2. Hazard(s) identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Corrosive to metals
Skin Corrosion/irritation
Serious Eye Damage/Eye Irritation
Category 1
Category 2
Category 1
Label Elements
Signal Word
Danger
Hazard Statements
May be corrosive to metals
Causes skin irritation
Causes serious eye damage
______________________________________________________________________________________________
Page 1 / 7
Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
Precautionary Statements
Prevention
Keep only in original container
Wear eye/face protection
Wear protective gloves
Wash face, hands and any exposed skin thoroughly after handling
Skin
IF ON SKIN: Wash with plenty of soap and water
Take off contaminated clothing and wash before reuse
If skin irritation occurs: Get medical advice/attention
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor/physician
Storage
Store in corrosive resistant polypropylene container with a resistant inliner
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified
3. Composition/Information on Ingredients
Component
Water
Hydrochloric acid
CAS-No
7732-18-5
7647-01-0
Weight %
96.35
3.65
4. First-aid measures
General Advice
If symptoms persist, call a physician.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.
Inhalation
Move to fresh air. If breathing is difficult, give oxygen. Obtain medical attention.
Ingestion
Do not induce vomiting. Obtain medical attention.
Most important symptoms and
effects
Notes to Physician
May cause skin irritation and/or dermatitis.
Suitable Extinguishing Media
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
Unsuitable Extinguishing Media
No information available
Treat symptomatically
5. Fire-fighting measures
Flash Point
Method -
Not applicable
No information available
No information available
Autoignition Temperature
Explosion Limits
No data available
Upper
No data available
Lower
Sensitivity to Mechanical Impact No information available
______________________________________________________________________________________________
Page 2 / 7
Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
Sensitivity to Static Discharge
No information available
Specific Hazards Arising from the Chemical
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Keep
product and empty container away from heat and sources of ignition.
Hazardous Combustion Products
Hydrogen chloride gas Thermal decomposition can lead to release of irritating gases and vapors
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
NFPA
Health
2
Flammability
0
Instability
0
Physical hazards
N/A
6. Accidental release measures
Use personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on
skin, or on clothing.
Avoid release to the environment. See Section 12 for additional ecological information.
Personal Precautions
Environmental Precautions
Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
Up
7. Handling and storage
Handling
Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on
skin, or on clothing. Avoid ingestion and inhalation.
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area.
8. Exposure controls / personal protection
Exposure Guidelines
Component
Hydrochloric acid
ACGIH TLV
Ceiling: 2 ppm
OSHA PEL
Ceiling: 5 ppm
Ceiling: 7 mg/m3
(Vacated) Ceiling: 5 ppm
(Vacated) Ceiling: 7 mg/m3
NIOSH IDLH
IDLH: 50 ppm
Ceiling: 5 ppm
Ceiling: 7 mg/m3
Mexico OEL (TWA)
Ceiling: 5 ppm
Ceiling: 7 mg/m3
Legend
ACGIH - American Conference of Governmental Industrial Hygienists
NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health
Engineering Measures
Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations
and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection
Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
______________________________________________________________________________________________
Page 3 / 7
Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Handle in accordance with good industrial hygiene and safety practice.
Hygiene Measures
9. Physical and chemical properties
Liquid
Clear
pungent
No information available
1.1 (0.1N)
0 °C / 32 °F
100 °C / 212 °F
Not applicable
No information available
Not applicable
Physical State
Appearance
Odor
Odor Threshold
pH
Melting Point/Range
Boiling Point/Range
Flash Point
Evaporation Rate
Flammability (solid,gas)
Flammability or explosive limits
Upper
Lower
Vapor Pressure
Vapor Density
Specific Gravity
Solubility
Partition coefficient; n-octanol/water
Autoignition Temperature
Decomposition Temperature
Viscosity
Molecular Formula
Molecular Weight
No data available
No data available
No information available
No information available
1.0 - 1.2
Soluble in water
No data available
No information available
No information available
No information available
HCl
36.46
10. Stability and reactivity
Reactive Hazard
None known, based on information available
Stability
Stable under normal conditions.
Conditions to Avoid
Incompatible products. Excess heat.
Incompatible Materials
Metals, Oxidizing agents, Reducing agents, Aldehydes
Hazardous Decomposition Products Hydrogen chloride gas, Thermal decomposition can lead to release of irritating gases and
vapors
Hazardous Polymerization
Hazardous polymerization does not occur.
Hazardous Reactions
None under normal processing.
11. Toxicological information
Acute Toxicity
Product Information
Oral LD50
Dermal LD50
Vapor LC50
Component Information
Component
Water
Hydrochloric acid
Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Based on ATE data, the classification criteria are not met. ATE > 20 mg/l.
LD50 Oral
238 – 277 mg/kg ( Rat )
LD50 Dermal
Not listed
> 5010 mg/kg ( Rabbit )
LC50 Inhalation
Not listed
1.68 mg/L ( Rat ) 1 h
______________________________________________________________________________________________
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Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
No information available
Toxicologically Synergistic
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation
Causes eye burns; Irritating to skin
Sensitization
No information available
Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component
CAS-No
IARC
Water
7732-18-5
Not listed
Hydrochloric acid
7647-01-0
Not listed
IARC: (International Agency for Research on Cancer)
NTP
ACGIH
OSHA
Not listed
Not listed
Not listed
Not listed
Not listed
Not listed
IARC: (International Agency for Research on Cancer)
Group 1 – Carcinogenic to Humans
Group 2A – Probably Carcinogenic to Humans
Group 2B – Possibly Carcinogenic to Humans
Mutagenic Effects
Mutagenic effects have occured in microorganisms.
Reproductive Effects
Experiments have shown reproductive toxicity effects on laboratory animals.
Developmental Effects
Developmental effects have occurred in experimental animals.
Teratogenicity
Teratogenic effects have occurred in experimental animals.
STOT – single exposure
STOT – repeated exposure
None known
None known
Aspiration hazard
No information available
Mexico
Not listed
Not listed
Symptoms / effects,both acute and No information available
delayed
Endocrine Disruptor Information
No information available
Other Adverse Effects
See actual entry in RTECS for complete information.
12. Ecological information
Ecotoxicity
.
Component
Hydrochloric acid
Freshwater Algae
–
Freshwater Fish
282 mg/L LC50 96 h
Gambusia affinis
mg/L LC50 48 h Leucscus
idus
Microtox
–
Water Flea
56mg/L EC50 72h Daphnia
Persistence and Degradability
Soluble in water Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation
No information available.
Mobility
Will likely be mobile in the environment due to its water solubility.
Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.
13. Disposal considerations
14. Transport information
DOT
UN-No
UN1789
______________________________________________________________________________________________
Page 5 / 7
Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
HYDROCHLORIC ACID SOLUTION
8
III
Proper Shipping Name
Hazard Class
Packing Group
TDG
UN-No
Proper Shipping Name
Hazard Class
Packing Group
IATA
UN-No
Proper Shipping Name
Hazard Class
Packing Group
IMDG/IMO
UN-No
Proper Shipping Name
Hazard Class
Packing Group
UN1789
HYDROCHLORIC ACID SOLUTION
8
III
UN1789
HYDROCHLORIC ACID SOLUTION
8
III
UN1789
HYDROCHLORIC ACID SOLUTION
8
III
15. Regulatory information
International Inventories
Component
Water
Hydrochloric acid
TSCA
X
X
DSL
X
X
NDSL EINECS ELINCS
231-791-2
231-595-7
–
NLP
PICCS
X
X
ENCS
X
AICS
X
X
IECSC
X
X
KECL
X
X
Legend:
X – Listed
E – Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.
F – Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.
N – Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated
polymer made with any free-radical initiator regardless of the amount used.
P – Indicates a commenced PMN substance
R – Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
S – Indicates a substance that is identified in a proposed or final Significant New Use Rule
T – Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU – Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base
Production and Site Reports (40 CFR 710(B).
Y1 – Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 – Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants
that comprises one of the eligibility criteria for the exemption rule.
U.S. Federal Regulations
Not applicable
TSCA 12(b)
SARA 313
Component
CAS-No
Weight %
Hydrochloric acid
7647-01-0
3.65
SARA 311/312 Hazard Categories
CWA (Clean Water Act)
Component
Hydrochloric acid
Clean Air Act
Component
Hydrochloric acid
SARA 313 – Threshold
Values %
1.0
See section 2 for more information
CWA – Hazardous
Substances
X
CWA – Reportable
Quantities
5000 lb
HAPS Data
X
CWA – Toxic Pollutants CWA – Priority Pollutants
–
Class 1 Ozone Depletors
–
Class 2 Ozone Depletors
–
______________________________________________________________________________________________
Page 6 / 7
Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
OSHA Occupational Safety and Health Administration
Specifically Regulated Chemicals
–
Component
Hydrochloric acid
Highly Hazardous Chemicals
TQ: 5000 lb
This material, as supplied, contains one or more substances regulated as a hazardous
substance under the Comprehensive Environmental Response Compensation and Liability
Act (CERCLA) (40 CFR 302)
CERCLA
Component
Hydrochloric acid
California Proposition 65
U.S. State Right-to-Know
Regulations
Component
Water
Hydrochloric acid
Hazardous Substances RQs
5000 lb
CERCLA EHS RQs
5000 lb
This product does not contain any Proposition 65 chemicals
Massachusetts
X
New Jersey
X
Pennsylvania
X
X
Illinois
X
Rhode Island
X
U.S. Department of Transportation
Reportable Quantity (RQ):
DOT Marine Pollutant
DOT Severe Marine Pollutant
Y
N
N
U.S. Department of Homeland Security
This product contains the following DHS chemicals:
Component
Hydrochloric acid
DHS Chemical Facility Anti-Terrorism Standard
0 lb STQ (anhydrous); 11250 lb STQ (37% concentration or
greater)
Other International Regulations
Mexico – Grade
No information available
Prepared By
Regulatory Affairs
Thermo Fisher Scientific
Email: EMSDS.RA@thermofisher.com
Creation Date
Revision Date
Print Date
Revision Summary
15-Feb-2010
18-Jan-2018
18-Jan-2018
This document has been updated to comply with the US OSHA HazCom 2012 Standard
replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
Harmonized System of Classification and Labeling of Chemicals (GHS).
16. Other information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text
End of SDS
______________________________________________________________________________________________
Page 7 / 7
SIGMA-ALDRICH
sigma-aldrich.com
SAFETY DATA SHEET
Version 5.8
Revision Date 09/23/2016
Print Date 02/25/2018
1. PRODUCT AND COMPANY IDENTIFICATION
1.1
1.2
Product identifiers
Product name
:
Reagent alcohol
Product Number
Brand
:
:
362808
Aldrich
CAS-No.
:
64-17-5
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
1.3
1.4
:
Laboratory chemicals, Synthesis of substances
Details of the supplier of the safety data sheet
Company
:
Sigma-Aldrich
3050 Spruce Street
SAINT LOUIS MO 63103
USA
Telephone
Fax
:
:
+1 800-325-5832
+1 800-325-5052
Emergency telephone number
Emergency Phone #
:
+1-703-527-3887 (CHEMTREC)
2. HAZARDS IDENTIFICATION
2.1
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 2), H225
Acute toxicity, Oral (Category 4), H302
Eye irritation (Category 2A), H319
Specific target organ toxicity – single exposure (Category 1), H370
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2
GHS Label elements, including precautionary statements
Pictogram
Signal word
Danger
Hazard statement(s)
H225
H302
H319
H370
Highly flammable liquid and vapour.
Harmful if swallowed.
Causes serious eye irritation.
Causes damage to organs.
Precautionary statement(s)
P210
P233
P240
P241
P242
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ ventilating/ lighting/ equipment.
Use only non-sparking tools.
Aldrich – 362808
Page 1 of 11
P243
P260
P264
P270
P280
P301 + P312 + P330
Take precautionary measures against static discharge.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves/ eye protection/ face protection.
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
Rinse mouth.
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
IF exposed: Call a POISON CENTER or doctor/ physician.
If eye irritation persists: Get medical advice/ attention.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to
extinguish.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/ container to an approved waste disposal plant.
P303 + P361 + P353
P305 + P351 + P338
P307 + P311
P337 + P313
P370 + P378
P403 + P235
P405
P501
2.3
Hazards not otherwise classified (HNOC) or not covered by GHS – none
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2
Mixtures
Synonyms
:
Absolute alcohol
Ethyl alcohol, Reagent alcohol
Formula
Molecular weight
:
:
C2H6O
46.07 g/mol
Hazardous components
Component
Classification
Concentration
Ethanol
CAS-No.
EC-No.
Index-No.
64-17-5
200-578-6
603-002-00-5
Flam. Liq. 2; Eye Irrit. 2A;
H225, H319
>= 90 – = 5 – < 10 %
2-Propanol
CAS-No.
EC-No.
Index-No.
67-63-0
200-661-7
603-117-00-0
Flam. Liq. 2; Eye Irrit. 2A;
STOT SE 3; H225, H319,
H336
>= 5 – < 10 %
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
4.1
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
Aldrich - 362808
Page 2 of 11
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a
physician.
4.2
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3
Indication of any immediate medical attention and special treatment needed
No data available
5. FIREFIGHTING MEASURES
5.1
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2
Special hazards arising from the substance or mixture
No data available
5.3
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4
Further information
Use water spray to cool unopened containers.
6. ACCIDENTAL RELEASE MEASURES
6.1
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all
sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
For personal protection see section 8.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in
container for disposal according to local regulations (see section 13).
6.4
Reference to other sections
For disposal see section 13.
7. HANDLING AND STORAGE
7.1
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Use explosion-proof equipment.Keep away from sources of ignition - No smoking.Take measures to prevent the build
up of electrostatic charge.
For precautions see section 2.2.
7.2
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage.
Moisture sensitive. Handle and store under inert gas.
7.3
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Aldrich - 362808
Page 3 of 11
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1
Control parameters
Components with workplace control parameters
Component
CAS-No.
Value
Control
parameters
Ethanol
64-17-5
TWA
1,000.000000
ppm
Remarks
Methanol
67-56-1
Basis
USA. ACGIH Threshold Limit Values
(TLV)
Upper Respiratory Tract irritation
Confirmed animal carcinogen with unknown relevance to humans
TWA
1,000 ppm
USA. OSHA - TABLE Z-1 Limits for
1,900 mg/m3
Air Contaminants - 1910.1000
TWA
1,000 ppm
USA. Occupational Exposure Limits
1,900 mg/m3
(OSHA) - Table Z-1 Limits for Air
Contaminants
The value in mg/m3 is approximate.
TWA
1,000.000000
USA. Occupational Exposure Limits
ppm
(OSHA) - Table Z-1 Limits for Air
1,900.000000
Contaminants
mg/m3
The value in mg/m3 is approximate.
TWA
1,000.000000
USA. NIOSH Recommended
ppm
Exposure Limits
1,900.000000
mg/m3
STEL
1,000.000000
USA. ACGIH Threshold Limit Values
ppm
(TLV)
Upper Respiratory Tract irritation
Confirmed animal carcinogen with unknown relevance to humans
TWA
200.000000
USA. ACGIH Threshold Limit Values
ppm
(TLV)
Headache
Nausea
Dizziness
Eye damage
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Danger of cutaneous absorption
STEL
250.000000
USA. ACGIH Threshold Limit Values
ppm
(TLV)
Headache
Nausea
Dizziness
Eye damage
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Danger of cutaneous absorption
TWA
200.000000
USA. NIOSH Recommended
ppm
Exposure Limits
260.000000
mg/m3
Potential for dermal absorption
Aldrich - 362808
Page 4 of 11
ST
250.000000
USA. NIOSH Recommended
ppm
Exposure Limits
325.000000
mg/m3
Potential for dermal absorption
TWA
200.000000
USA. Occupational Exposure Limits
ppm
(OSHA) - Table Z-1 Limits for Air
260.000000
Contaminants
mg/m3
The value in mg/m3 is approximate.
TWA
200 ppm
USA. ACGIH Threshold Limit Values
(TLV)
Headache
Nausea
Dizziness
Eye damage
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Danger of cutaneous absorption
STEL
250 ppm
USA. ACGIH Threshold Limit Values
(TLV)
Headache
Nausea
Dizziness
Eye damage
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Danger of cutaneous absorption
TWA
200 ppm
USA. NIOSH Recommended
260 mg/m3
Exposure Limits
Potential for dermal absorption
ST
250 ppm
USA. NIOSH Recommended
325 mg/m3
Exposure Limits
Potential for dermal absorption
TWA
200 ppm
USA. Occupational Exposure Limits
260 mg/m3
(OSHA) - Table Z-1 Limits for Air
Contaminants
The value in mg/m3 is approximate.
STEL
250 ppm
USA. OSHA - TABLE Z-1 Limits for
325 mg/m3
Air Contaminants - 1910.1000
Skin notation
TWA
200 ppm
USA. OSHA - TABLE Z-1 Limits for
260 mg/m3
Air Contaminants - 1910.1000
Skin notation
C
1,000 ppm
California permissible exposure
limits for chemical contaminants
(Title 8, Article 107)
Skin
PEL
200 ppm
California permissible exposure
260 mg/m3
limits for chemical contaminants
(Title 8, Article 107)
Skin
STEL
250 ppm
California permissible exposure
325 mg/m3
limits for chemical contaminants
(Title 8, Article 107)
Skin
Aldrich - 362808
Page 5 of 11
2-Propanol
67-63-0
TWA
200.000000
ppm
USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
Upper Respiratory Tract irritation
Eye irritation
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Not classifiable as a human carcinogen
TWA
200 ppm
USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
Upper Respiratory Tract irritation
Eye irritation
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Not classifiable as a human carcinogen
STEL
400 ppm
USA. ACGIH Threshold Limit Values
(TLV)
Central Nervous System impairment
Upper Respiratory Tract irritation
Eye irritation
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Not classifiable as a human carcinogen
STEL
400.000000
USA. ACGIH Threshold Limit Values
ppm
(TLV)
Central Nervous System impairment
Upper Respiratory Tract irritation
Eye irritation
Substances for which there is a Biological Exposure Index or Indices
(see BEI® section)
Not classifiable as a human carcinogen
TWA
400.000000
USA. Occupational Exposure Limits
ppm
(OSHA) - Table Z-1 Limits for Air
980.000000
Contaminants
mg/m3
The value in mg/m3 is approximate.
TWA
400.000000
USA. NIOSH Recommended
ppm
Exposure Limits
980.000000
mg/m3
ST
500.000000
USA. NIOSH Recommended
ppm
Exposure Limits
1,225.000000
mg/m3
PEL
400 ppm
California permissible exposure
980 mg/m3
limits for chemical contaminants
(Title 8, Article 107)
STEL
500 ppm
California permissible exposure
1,225 mg/m3
limits for chemical contaminants
(Title 8, Article 107)
Biological occupational exposure limits
Component
CAS-No.
Parameters
Methanol
Aldrich - 362808
67-56-1
Methanol
Value
Biological
specimen
Basis
15.0000
mg/l
Urine
ACGIH - Biological
Exposure Indices
(BEI)
Page 6 of 11
Remarks
2-Propanol
8.2
67-63-0
End of shift (As soon as possible after exposure ceases)
Methanol
15 mg/l
Urine
ACGIH - Biological
Exposure Indices
(BEI)
End of shift (As soon as possible after exposure ceases)
Acetone
40.0000
Urine
ACGIH - Biological
mg/l
Exposure Indices
(BEI)
End of shift at end of workweek
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of
workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Full contact
Material: butyl-rubber
Minimum layer thickness: 0.3 mm
Break through time: 480 min
Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.2 mm
Break through time: 30 min
Material tested:Dermatril® P (KCL 743 / Aldrich Z677388, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method:
EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the
supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an
industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It
should not be construed as offering an approval for any specific use scenario.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of
protective equipment must be selected according to the concentration and amount of the dangerous substance
at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.
If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1
Information on basic physical and chemical properties
a)
Appearance
Form: liquid
b)
Odour
No data available
Aldrich - 362808
Page 7 of 11
9.2
c)
Odour Threshold
No data available
d)
pH
No data available
e)
Melting point/freezing
point
Melting point/range: -130 °C (-202 °F)
f)
Initial boiling point and
boiling range
78 °C (172 °F) at 1,013 hPa (760 mmHg)
g)
Flash point
9 °C (48 °F) - closed cup
h)
Evaporation rate
No data available
i)
Flammability (solid, gas) No data available
j)
Upper/lower
flammability or
explosive limits
Upper explosion limit: 24.5 %(V)
Lower explosion limit: 3.3 %(V)
k)
Vapour pressure
59.5 hPa (44.6 mmHg) at 20 °C (68 °F)
l)
Vapour density
No data available
m) Relative density
0.785 g/cm3
n)
Water solubility
No data available
o)
Partition coefficient: noctanol/water
No data available
p)
Auto-ignition
temperature
362 °C (684 °F)
q)
Decomposition
temperature
No data available
r)
Viscosity
No data available
s)
Explosive properties
No data available
t)
Oxidizing properties
No data available
Other safety information
No data available
10. STABILITY AND REACTIVITY
10.1
Reactivity
No data available
10.2
Chemical stability
Stable under recommended storage conditions.
10.3
Possibility of hazardous reactions
Vapours may form explosive mixture with air.
10.4
Conditions to avoid
Heat, flames and sparks.
10.5
Incompatible materials
Aluminium, Acids, Oxidizing agents, Alkali metals, Halogenated compounds, Ammonia, Acid chlorides, Acid
anhydrides, Reducing agents, Peroxides
10.6
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Other decomposition products - No data available
In the event of fire: see section 5
Aldrich - 362808
Page 8 of 11
11. TOXICOLOGICAL INFORMATION
11.1
Information on toxicological effects
Acute toxicity
No data available
Inhalation: No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated., Central nervous system depression, Gastrointestinal disturbance, Nausea, Dizziness, Headache,
narcosis, May cause convulsions.
Stomach - Irregularities - Based on Human Evidence
Kidney - Irregularities - Based on Human Evidence
Stomach - Irregularities - Based on Human Evidence (Ethanol)
Stomach - Irregularities - Based on Human Evidence (Methanol)
Kidney - Irregularities - Based on Human Evidence (2-Propanol)
12. ECOLOGICAL INFORMATION
12.1
Toxicity
No data available
12.2
Persistence and degradability
No data available
Aldrich - 362808
Page 9 of 11
12.3
Bioaccumulative potential
No data available
12.4
Mobility in soil
No data available
12.5
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6
Other adverse effects
No data available
13. DISPOSAL CONSIDERATIONS
13.1
Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this
material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a
licensed professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
DOT (US)
UN number: 1170
Class: 3
Proper shipping name: Ethanol solutions
Reportable Quantity (RQ):
Packing group: II
Poison Inhalation Hazard: No
IMDG
UN number: 1170
Class: 3
Proper shipping name: ETHANOL SOLUTION
Packing group: II
IATA
UN number: 1170
Class: 3
Proper shipping name: Ethanol solution
Packing group: II
EMS-No: F-E, S-D
15. REGULATORY INFORMATION
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
CAS-No.
Revision Date
Methanol
67-56-1
2007-07-01
2-Propanol
67-63-0
1987-01-01
SARA 311/312 Hazards
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
Ethanol
Methanol
2-Propanol
CAS-No.
64-17-5
67-56-1
67-63-0
Revision Date
2007-03-01
2007-07-01
1987-01-01
CAS-No.
64-17-5
67-56-1
67-63-0
Revision Date
2007-03-01
2007-07-01
1987-01-01
Pennsylvania Right To Know Components
Ethanol
Methanol
2-Propanol
Aldrich - 362808
Page 10 of 11
New Jersey Right To Know Components
Ethanol
Methanol
2-Propanol
California Prop. 65 Components
WARNING: This product contains a chemical known to the
State of California to cause birth defects or other reproductive
harm.
Methanol
CAS-No.
64-17-5
67-56-1
67-63-0
Revision Date
2007-03-01
2007-07-01
1987-01-01
CAS-No.
67-56-1
Revision Date
2012-03-16
16. OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.
Acute Tox.
Eye Irrit.
Flam. Liq.
H225
H301 + H311 +
H331
H302
H319
H336
H370
STOT SE
Acute toxicity
Eye irritation
Flammable liquids
Highly flammable liquid and vapour.
Toxic if swallowed, in contact with skin or if inhaled
Harmful if swallowed.
Causes serious eye irritation.
May cause drowsiness or dizziness.
Causes damage to organs.
Specific target organ toxicity - single exposure
HMIS Rating
Health hazard:
Chronic Health Hazard:
Flammability:
Physical Hazard
2
*
3
0
NFPA Rating
Health hazard:
Fire Hazard:
Reactivity Hazard:
2
3
0
Further information
Copyright 2016 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a
guide. The information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the
product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling
or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing
slip for additional terms and conditions of sale.
Preparation Information
Sigma-Aldrich Corporation
Product Safety – Americas Region
1-800-521-8956
Version: 5.8
Aldrich - 362808
Revision Date: 09/23/2016
Print Date: 02/25/2018
Page 11 of 11
SAFETY DATA SHEET
Creation Date 15-Feb-2010
Revision Date 18-Jan-2018
Revision Number 3
1. Identification
Product Name
Hydrochloric acid solution, 1N
Cat No. :
SA55; S748561
Synonyms
Muriatic acid solution; Hydrogen chloride solution (Certified)
Recommended Use
Uses advised against
Laboratory chemicals.
Not for food, drug, pesticide or biocidal product use
Details of the supplier of the safety data sheet
Company
Fisher Scientific
One Reagent Lane
Fair Lawn, NJ 07410
Tel: (201) 796-7100
Emergency Telephone Number
CHEMTRECÒ, Inside the USA: 800-424-9300
CHEMTRECÒ, Outside the USA: 001-703-527-3887
2. Hazard(s) identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Corrosive to metals
Skin Corrosion/irritation
Serious Eye Damage/Eye Irritation
Category 1
Category 2
Category 1
Label Elements
Signal Word
Danger
Hazard Statements
May be corrosive to metals
Causes skin irritation
Causes serious eye damage
______________________________________________________________________________________________
Page 1 / 7
Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
Precautionary Statements
Prevention
Keep only in original container
Wear eye/face protection
Wear protective gloves
Wash face, hands and any exposed skin thoroughly after handling
Skin
IF ON SKIN: Wash with plenty of soap and water
Take off contaminated clothing and wash before reuse
If skin irritation occurs: Get medical advice/attention
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor/physician
Storage
Store in corrosive resistant polypropylene container with a resistant inliner
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified
3. Composition/Information on Ingredients
Component
Water
Hydrochloric acid
CAS-No
7732-18-5
7647-01-0
Weight %
96.35
3.65
4. First-aid measures
General Advice
If symptoms persist, call a physician.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.
Inhalation
Move to fresh air. If breathing is difficult, give oxygen. Obtain medical attention.
Ingestion
Do not induce vomiting. Obtain medical attention.
Most important symptoms and
effects
Notes to Physician
May cause skin irritation and/or dermatitis.
Suitable Extinguishing Media
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
Unsuitable Extinguishing Media
No information available
Treat symptomatically
5. Fire-fighting measures
Flash Point
Method -
Not applicable
No information available
No information available
Autoignition Temperature
Explosion Limits
No data available
Upper
No data available
Lower
Sensitivity to Mechanical Impact No information available
______________________________________________________________________________________________
Page 2 / 7
Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
Sensitivity to Static Discharge
No information available
Specific Hazards Arising from the Chemical
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Keep
product and empty container away from heat and sources of ignition.
Hazardous Combustion Products
Hydrogen chloride gas Thermal decomposition can lead to release of irritating gases and vapors
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
NFPA
Health
2
Flammability
0
Instability
0
Physical hazards
N/A
6. Accidental release measures
Use personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on
skin, or on clothing.
Avoid release to the environment. See Section 12 for additional ecological information.
Personal Precautions
Environmental Precautions
Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
Up
7. Handling and storage
Handling
Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on
skin, or on clothing. Avoid ingestion and inhalation.
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area.
8. Exposure controls / personal protection
Exposure Guidelines
Component
Hydrochloric acid
ACGIH TLV
Ceiling: 2 ppm
OSHA PEL
Ceiling: 5 ppm
Ceiling: 7 mg/m3
(Vacated) Ceiling: 5 ppm
(Vacated) Ceiling: 7 mg/m3
NIOSH IDLH
IDLH: 50 ppm
Ceiling: 5 ppm
Ceiling: 7 mg/m3
Mexico OEL (TWA)
Ceiling: 5 ppm
Ceiling: 7 mg/m3
Legend
ACGIH - American Conference of Governmental Industrial Hygienists
NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health
Engineering Measures
Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations
and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection
Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
______________________________________________________________________________________________
Page 3 / 7
Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Handle in accordance with good industrial hygiene and safety practice.
Hygiene Measures
9. Physical and chemical properties
Liquid
Clear
pungent
No information available
1.1 (0.1N)
0 °C / 32 °F
100 °C / 212 °F
Not applicable
No information available
Not applicable
Physical State
Appearance
Odor
Odor Threshold
pH
Melting Point/Range
Boiling Point/Range
Flash Point
Evaporation Rate
Flammability (solid,gas)
Flammability or explosive limits
Upper
Lower
Vapor Pressure
Vapor Density
Specific Gravity
Solubility
Partition coefficient; n-octanol/water
Autoignition Temperature
Decomposition Temperature
Viscosity
Molecular Formula
Molecular Weight
No data available
No data available
No information available
No information available
1.0 - 1.2
Soluble in water
No data available
No information available
No information available
No information available
HCl
36.46
10. Stability and reactivity
Reactive Hazard
None known, based on information available
Stability
Stable under normal conditions.
Conditions to Avoid
Incompatible products. Excess heat.
Incompatible Materials
Metals, Oxidizing agents, Reducing agents, Aldehydes
Hazardous Decomposition Products Hydrogen chloride gas, Thermal decomposition can lead to release of irritating gases and
vapors
Hazardous Polymerization
Hazardous polymerization does not occur.
Hazardous Reactions
None under normal processing.
11. Toxicological information
Acute Toxicity
Product Information
Oral LD50
Dermal LD50
Vapor LC50
Component Information
Component
Water
Hydrochloric acid
Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Based on ATE data, the classification criteria are not met. ATE > 20 mg/l.
LD50 Oral
238 – 277 mg/kg ( Rat )
LD50 Dermal
Not listed
> 5010 mg/kg ( Rabbit )
LC50 Inhalation
Not listed
1.68 mg/L ( Rat ) 1 h
______________________________________________________________________________________________
Page 4 / 7
Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
No information available
Toxicologically Synergistic
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation
Causes eye burns; Irritating to skin
Sensitization
No information available
Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component
CAS-No
IARC
Water
7732-18-5
Not listed
Hydrochloric acid
7647-01-0
Not listed
IARC: (International Agency for Research on Cancer)
NTP
ACGIH
OSHA
Not listed
Not listed
Not listed
Not listed
Not listed
Not listed
IARC: (International Agency for Research on Cancer)
Group 1 – Carcinogenic to Humans
Group 2A – Probably Carcinogenic to Humans
Group 2B – Possibly Carcinogenic to Humans
Mutagenic Effects
Mutagenic effects have occured in microorganisms.
Reproductive Effects
Experiments have shown reproductive toxicity effects on laboratory animals.
Developmental Effects
Developmental effects have occurred in experimental animals.
Teratogenicity
Teratogenic effects have occurred in experimental animals.
STOT – single exposure
STOT – repeated exposure
None known
None known
Aspiration hazard
No information available
Mexico
Not listed
Not listed
Symptoms / effects,both acute and No information available
delayed
Endocrine Disruptor Information
No information available
Other Adverse Effects
See actual entry in RTECS for complete information.
12. Ecological information
Ecotoxicity
.
Component
Hydrochloric acid
Freshwater Algae
–
Freshwater Fish
282 mg/L LC50 96 h
Gambusia affinis
mg/L LC50 48 h Leucscus
idus
Microtox
–
Water Flea
56mg/L EC50 72h Daphnia
Persistence and Degradability
Soluble in water Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation
No information available.
Mobility
Will likely be mobile in the environment due to its water solubility.
Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.
13. Disposal considerations
14. Transport information
DOT
UN-No
UN1789
______________________________________________________________________________________________
Page 5 / 7
Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
HYDROCHLORIC ACID SOLUTION
8
III
Proper Shipping Name
Hazard Class
Packing Group
TDG
UN-No
Proper Shipping Name
Hazard Class
Packing Group
IATA
UN-No
Proper Shipping Name
Hazard Class
Packing Group
IMDG/IMO
UN-No
Proper Shipping Name
Hazard Class
Packing Group
UN1789
HYDROCHLORIC ACID SOLUTION
8
III
UN1789
HYDROCHLORIC ACID SOLUTION
8
III
UN1789
HYDROCHLORIC ACID SOLUTION
8
III
15. Regulatory information
International Inventories
Component
Water
Hydrochloric acid
TSCA
X
X
DSL
X
X
NDSL EINECS ELINCS
231-791-2
231-595-7
–
NLP
PICCS
X
X
ENCS
X
AICS
X
X
IECSC
X
X
KECL
X
X
Legend:
X – Listed
E – Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.
F – Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.
N – Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated
polymer made with any free-radical initiator regardless of the amount used.
P – Indicates a commenced PMN substance
R – Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
S – Indicates a substance that is identified in a proposed or final Significant New Use Rule
T – Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU – Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base
Production and Site Reports (40 CFR 710(B).
Y1 – Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 – Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants
that comprises one of the eligibility criteria for the exemption rule.
U.S. Federal Regulations
Not applicable
TSCA 12(b)
SARA 313
Component
CAS-No
Weight %
Hydrochloric acid
7647-01-0
3.65
SARA 311/312 Hazard Categories
CWA (Clean Water Act)
Component
Hydrochloric acid
Clean Air Act
Component
Hydrochloric acid
SARA 313 – Threshold
Values %
1.0
See section 2 for more information
CWA – Hazardous
Substances
X
CWA – Reportable
Quantities
5000 lb
HAPS Data
X
CWA – Toxic Pollutants CWA – Priority Pollutants
–
Class 1 Ozone Depletors
–
Class 2 Ozone Depletors
–
______________________________________________________________________________________________
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Revision Date 18-Jan-2018
Hydrochloric acid solution, 1N
______________________________________________________________________________________________
OSHA Occupational Safety and Health Administration
Specifically Regulated Chemicals
–
Component
Hydrochloric acid
Highly Hazardous Chemicals
TQ: 5000 lb
This material, as supplied, contains one or more substances regulated as a hazardous
substance under the Comprehensive Environmental Response Compensation and Liability
Act (CERCLA) (40 CFR 302)
CERCLA
Component
Hydrochloric acid
California Proposition 65
U.S. State Right-to-Know
Regulations
Component
Water
Hydrochloric acid
Hazardous Substances RQs
5000 lb
CERCLA EHS RQs
5000 lb
This product does not contain any Proposition 65 chemicals
Massachusetts
X
New Jersey
X
Pennsylvania
X
X
Illinois
X
Rhode Island
X
U.S. Department of Transportation
Reportable Quantity (RQ):
DOT Marine Pollutant
DOT Severe Marine Pollutant
Y
N
N
U.S. Department of Homeland Security
This product contains the following DHS chemicals:
Component
Hydrochloric acid
DHS Chemical Facility Anti-Terrorism Standard
0 lb STQ (anhydrous); 11250 lb STQ (37% concentration or
greater)
Other International Regulations
Mexico – Grade
No information available
Prepared By
Regulatory Affairs
Thermo Fisher Scientific
Email: EMSDS.RA@thermofisher.com
Creation Date
Revision Date
Print Date
Revision Summary
15-Feb-2010
18-Jan-2018
18-Jan-2018
This document has been updated to comply with the US OSHA HazCom 2012 Standard
replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
Harmonized System of Classification and Labeling of Chemicals (GHS).
16. Other information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text
End of SDS
______________________________________________________________________________________________
Page 7 / 7
SAFETY DATA SHEET
Creation Date 20-Apr-2010
Revision Date 18-Jan-2018
Revision Number 4
1. Identification
Product Name
Propylene oxide
Cat No. :
O4332-1; NC0559300
CAS-No
Synonyms
75-56-9
1,2-Epoxypropane; Methyloxirane; Propene oxide (Reagent)
Recommended Use
Uses advised against
Laboratory chemicals.
Not for food, drug, pesticide or biocidal product use
Details of the supplier of the safety data sheet
Company
Fisher Scientific
One Reagent Lane
Fair Lawn, NJ 07410
Tel: (201) 796-7100
Emergency Telephone Number
CHEMTRECÒ, Inside the USA: 800-424-9300
CHEMTRECÒ, Outside the USA: 001-703-527-3887
2. Hazard(s) identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Flammable liquids
Acute oral toxicity
Acute dermal toxicity
Acute Inhalation Toxicity – Vapors
Serious Eye Damage/Eye Irritation
Germ Cell Mutagenicity
Carcinogenicity
Specific target organ toxicity (single exposure)
Target Organs – Respiratory system.
Category 1
Category 4
Category 3
Category 3
Category 2
Category 1B
Category 1B
Category 3
Label Elements
Signal Word
Danger
Hazard Statements
Extremely flammable liquid and vapor
Harmful if swallowed
Toxic in contact with skin
Causes serious eye irritation
Toxic if inhaled
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Revision Date 18-Jan-2018
Propylene oxide
______________________________________________________________________________________________
May cause respiratory irritation
May cause genetic defects
May cause cancer
Precautionary Statements
Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Wear eye/face protection
Keep away from heat/sparks/open flames/hot surfaces. – No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool
Response
IF exposed or concerned: Get medical attention/advice
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician
Skin
Call a POISON CENTER or doctor/physician if you feel unwell
Wash contaminated clothing before reuse
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Hazardous polymerization may occur
WARNING. Cancer – https://www.p65warnings.ca.gov/.
3. Composition/Information on Ingredients
Component
CAS-No
Weight %
______________________________________________________________________________________________
Page 2 / 8
Revision Date 18-Jan-2018
Propylene oxide
______________________________________________________________________________________________
Propylene oxide
75-56-9
>95
4. First-aid measures
General Advice
Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Eye Contact
In the case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. Immediate medical
attention is required.
Inhalation
Move to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth
method if victim ingested or inhaled the substance; give artificial respiration with the aid of a
pocket mask equipped with a one-way valve or other proper respiratory medical device.
Immediate medical attention is required.
Ingestion
Do not induce vomiting. Call a physician or Poison Control Center immediately.
Most important symptoms and
effects
Notes to Physician
. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,
tiredness, nausea and vomiting
Treat symptomatically
Suitable Extinguishing Media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Cool closed
containers exposed to fire with water spray.
Unsuitable Extinguishing Media
No information available
5. Fire-fighting measures
Flash Point
-37 °C / -34.6 °F
Method –
No information available
Autoignition Temperature
430 °C / 806 °F
Explosion Limits
37 vol %
Upper
2.3 vol %
Lower
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Extremely flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to
source of ignition and flash back.
Hazardous Combustion Products
Carbon monoxide (CO) Carbon dioxide (CO2)
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Thermal decomposition can lead to release of irritating gases and vapors.
NFPA
Health
3
Flammability
4
Instability
2
Physical hazards
N/A
6. Accidental release measures
Personal Precautions
Use personal protective equipment. Ensure adequate ventilation. Remove all sources of
ignition. Take precautionary measures against static discharges. Keep people away from
______________________________________________________________________________________________
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Revision Date 18-Jan-2018
Propylene oxide
______________________________________________________________________________________________
and upwind of spill/leak. Evacuate personnel to safe areas.
Should not be released into the environment.
Environmental Precautions
Methods for Containment and Clean Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.
Up
7. Handling and storage
Handling
Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Use only
under a chemical fume hood. Do not breathe vapors or spray mist. Do not ingest. Keep
away from open flames, hot surfaces and sources of ignition. Use explosion-proof
equipment. Use only non-sparking tools. To avoid ignition of vapors by static electricity
discharge, all metal parts of the equipment must be grounded. Take precautionary
measures against static discharges.
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place. Flammables area.
Keep away from heat and sources of ignition.
8. Exposure controls / personal protection
Exposure Guidelines
Component
Propylene oxide
ACGIH TLV
TWA: 2 ppm
OSHA PEL
(Vacated) TWA: 20 ppm
(Vacated) TWA: 50 mg/m3
TWA: 100 ppm
TWA: 240 mg/m3
NIOSH IDLH
IDLH: 400 ppm
Mexico OEL (TWA)
TWA: 20 ppm
TWA: 50 mg/m3
Legend
ACGIH – American Conference of Governmental Industrial Hygienists
OSHA – Occupational Safety and Health Administration
NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health
Engineering Measures
Use only under a chemical fume hood. Ensure that eyewash stations and safety showers
are close to the workstation location. Use explosion-proof
electrical/ventilating/lighting/equipment. Ensure adequate ventilation, especially in confined
areas.
Personal Protective Equipment
Eye/face Protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection
Long sleeved clothing.
Respiratory Protection
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.
9. Physical and chemical properties
Physical State
Appearance
Odor
Odor Threshold
pH
Melting Point/Range
Liquid
Colorless
aromatic
No information available
No information available
-112 °C / -169.6 °F
______________________________________________________________________________________________
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Revision Date 18-Jan-2018
Propylene oxide
______________________________________________________________________________________________
34 °C / 93.2 °F
-37 °C / -34.6 °F
No information available
Not applicable
Boiling Point/Range
Flash Point
Evaporation Rate
Flammability (solid,gas)
Flammability or explosive limits
Upper
Lower
Vapor Pressure
Vapor Density
Specific Gravity
Solubility
Partition coefficient; n-octanol/water
Autoignition Temperature
Decomposition Temperature
Viscosity
Molecular Formula
Molecular Weight
37 vol %
2.3 vol %
590 mbar @ 20 °C
2.0
0.830
Soluble in water
No data available
430 °C / 806 °F
No information available
0.32 mPa s at 20 °C
C3 H6 O
58.08
10. Stability and reactivity
Reactive Hazard
Yes
Stability
Stable under normal conditions.
Conditions to Avoid
Incompatible products. Excess heat. Keep away from open flames, hot surfaces and
sources of ignition.
Incompatible Materials
Strong oxidizing agents, Acids, Bases, Amines, copper, Copper alloys, Peroxides
Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2)
Hazardous Polymerization
Hazardous polymerization may occur.
Hazardous Reactions
None under normal processing.
11. Toxicological information
Acute Toxicity
Product Information
Component Information
Component
Propylene oxide
LD50 Oral
LD50 = 520 mg/kg ( Rat )
LD50 Dermal
LD50 = 1244 mg/kg ( Rabbit )
LC50 Inhalation
9.48 mg/L ( Rat ) 4 h
No information available
Toxicologically Synergistic
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation
Irritating to eyes and respiratory system
Sensitization
No information available
Carcinogenicity
May cause cancer. The table below indicates whether each agency has listed any
ingredient as a carcinogen.
Component
Propylene oxide
CAS-No
75-56-9
IARC
Group 2B
IARC: (International Agency for Research on Cancer)
NTP
ACGIH
OSHA
Reasonably
A3
X
Anticipated
IARC: (International Agency for Research on Cancer)
Group 1 – Carcinogenic to Humans
Group 2A – Probably Carcinogenic to Humans
Mexico
A3
______________________________________________________________________________________________
Page 5 / 8
Revision Date 18-Jan-2018
Propylene oxide
______________________________________________________________________________________________
NTP: (National Toxicity Program)
ACGIH: (American Conference of Governmental Industrial
Hygienists)
Mexico – Occupational Exposure Limits – Carcinogens
Group 2B – Possibly Carcinogenic to Humans
NTP: (National Toxicity Program)
Known – Known Carcinogen
Reasonably Anticipated – Reasonably Anticipated to be a Human
Carcinogen
A1 – Known Human Carcinogen
A2 – Suspected Human Carcinogen
A3 – Animal Carcinogen
ACGIH: (American Conference of Governmental Industrial Hygienists)
Mexico – Occupational Exposure Limits – Carcinogens
A1 – Confirmed Human Carcinogen
A2 – Suspected Human Carcinogen
A3 – Confirmed Animal Carcinogen
A4 – Not Classifiable as a Human Carcinogen
A5 – Not Suspected as a Human Carcinogen
Mutagenic Effects
May cause heritable genetic damage
Reproductive Effects
No information available.
Developmental Effects
No information available.
Teratogenicity
No information available.
STOT – single exposure
STOT – repeated exposure
Respiratory system
None known
Aspiration hazard
No information available
Symptoms / effects,both acute and Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,
tiredness, nausea and vomiting
delayed
Endocrine Disruptor Information
No information available
Other Adverse Effects
The toxicological properties have not been fully investigated.
12. Ecological information
Ecotoxicity
Do not empty into drains. .
Component
Propylene oxide
Freshwater Algae
EC50: = 240 mg/L, 96h
(Pseudokirchneriella
subcapitata)
Freshwater Fish
Microtox
LC50: = 215 mg/L, 96h static EC50 = 3300 mg/L 160 min
(Lepomis macrochirus)
Persistence and Degradability
Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation
No information available.
Mobility
Will likely be mobile in the environment due to its volatility.
Component
Propylene oxide
Water Flea
EC50: = 350 mg/L, 48h
(Daphnia magna)
log Pow
0.08
13. Disposal considerations
Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.
14. Transport information
DOT
UN-No
UN1280
______________________________________________________________________________________________
Page 6 / 8
Revision Date 18-Jan-2018
Propylene oxide
______________________________________________________________________________________________
PROPYLENE OXIDE
3
I
Proper Shipping Name
Hazard Class
Packing Group
TDG
UN-No
Proper Shipping Name
Hazard Class
Packing Group
IATA
UN-No
Proper Shipping Name
Hazard Class
Packing Group
IMDG/IMO
UN-No
Proper Shipping Name
Hazard Class
Packing Group
UN1280
PROPYLENE OXIDE
3
I
UN1280
PROPYLENE OXIDE
3
I
UN1280
PROPYLENE OXIDE
3
I
15. Regulatory information
All of the components in the product are on the following Inventory lists: X = listed
International Inventories
Component
Propylene oxide
TSCA
X
DSL
X
NDSL EINECS ELINCS
200-879-2
–
NLP
PICCS
X
ENCS
X
AICS
X
IECSC
X
KECL
X
Legend:
X – Listed
E – Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.
F – Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.
N – Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated
polymer made with any free-radical initiator regardless of the amount used.
P – Indicates a commenced PMN substance
R – Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
S – Indicates a substance that is identified in a proposed or final Significant New Use Rule
T – Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU – Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base
Production and Site Reports (40 CFR 710(B).
Y1 – Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 – Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants
that comprises one of the eligibility criteria for the exemption rule.
U.S. Federal Regulations
Not applicable
TSCA 12(b)
SARA 313
Component
CAS-No
Weight %
Propylene oxide
75-56-9
>95
SARA 311/312 Hazard Categories
CWA (Clean Water Act)
Component
Propylene oxide
Clean Air Act
Component
Propylene oxide
SARA 313 – Threshold
Values %
0.1
See section 2 for more information
CWA – Hazardous
Substances
X
CWA – Reportable
Quantities
100 lb
HAPS Data
X
CWA – Toxic Pollutants CWA – Priority Pollutants
–
Class 1 Ozone Depletors
–
Class 2 Ozone Depletors
–
______________________________________________________________________________________________
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Revision Date 18-Jan-2018
Propylene oxide
______________________________________________________________________________________________
OSHA Occupational Safety and Health Administration
Not applicable
This material, as supplied, contains one or more substances regulated as a hazardous
substance under the Comprehensive Environmental Response Compensation and Liability
Act (CERCLA) (40 CFR 302)
CERCLA
Hazardous Substances RQs
100 lb
Component
Propylene oxide
California Proposition 65
Component
Propylene oxide
U.S. State Right-to-Know
Regulations
Component
Propylene oxide
CERCLA EHS RQs
100 lb
This product contains the following proposition 65 chemicals
CAS-No
75-56-9
California Prop. 65
Carcinogen
Massachusetts
X
New Jersey
X
Prop 65 NSRL
–
Pennsylvania
X
Illinois
X
Category
Carcinogen
Rhode Island
X
U.S. Department of Transportation
Reportable Quantity (RQ):
DOT Marine Pollutant
DOT Severe Marine Pollutant
Y
N
N
U.S. Department of Homeland Security
This product contains the following DHS chemicals:
Component
Propylene oxide
Other International Regulations
DHS Chemical Facility Anti-Terrorism Standard
7500 lb STQ
Mexico – Grade
Severe risk, Grade 4
Prepared By
Regulatory Affairs
Thermo Fisher Scientific
Email: EMSDS.RA@thermofisher.com
Creation Date
Revision Date
Print Date
Revision Summary
20-Apr-2010
18-Jan-2018
18-Jan-2018
This document has been updated to comply with the US OSHA HazCom 2012 Standard
replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
Harmonized System of Classification and Labeling of Chemicals (GHS).
16. Other information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text
End of SDS
______________________________________________________________________________________________
Page 8 / 8
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